IGNOU MCHE-013 Supramolecular Chemistry | SOLVED ASSIGNMENT 2026-27

IGNOU MCHE-013 Supramolecular Chemistry · 2026–27 Session

MCHE-013 introduces students to the fascinating field of Supramolecular Chemistry, which focuses on chemical systems formed through non-covalent interactions between molecules. The course explores molecular recognition, host–guest chemistry, self-assembly, supramolecular structures, and the applications of these systems in areas such as catalysis, sensing, medicine, and nanotechnology.

The course helps students understand how weak intermolecular forces can control the structure, properties, and functions of complex molecular systems.

Course Code	Applicable Session	Maximum Marks	Assignment Code
MCHE-013	2026–27 Session	100	MCHE-013/TMA/2026-27

Key Areas of Study in MCHE-013:

1.    Introduction to Supramolecular Chemistry – Understand the concept, scope, and importance of supramolecular chemistry and its difference from molecular chemistry.

2.    Non-Covalent Interactions – Study hydrogen bonding, van der Waals forces, electrostatic interactions, π–π interactions, and hydrophobic interactions.

3.    Molecular Recognition and Host–Guest Chemistry – Understand how molecules recognize and selectively bind with one another through non-covalent interactions.

4.    Self-Assembly and Supramolecular Structures – Study the spontaneous organization of molecules into larger and ordered structures.

5.    Supramolecular Catalysis and Molecular Machines – Explore the role of supramolecular systems in catalysis, molecular devices, and molecular machines.

6.    Applications of Supramolecular Chemistry – Understand applications in drug delivery, sensors, nanotechnology, materials science, and biomedical chemistry.

IGNOU MCHE-013 Supramolecular Chemistry | SOLVED ASSIGNMENT 2026-27

Note: Attempt all questions. The marks for each question are indicated against it.

Q1. a) Explain dipole-dipole interactions in supramolecular chemistry with a suitable example. What is its energy range and why are they important? When are they helpful in molecular recognition?

b) Explain the lock and key principle of binding in supramolecular chemistry with suitable diagrams.

Q2. a) What are the different types of supramolecular complexes? Illustrate your answer.

b) Give the differences between enthalpy-driven and entropy-driven binding processes.

Q3. a) Distinguish between clatharate and clathrand? What are cucurbiturils? Draw any one cucurbituril.

b) What are calixarenes? Draw the diagram for binding of sodium ion as guest to the oxygen of methyl ether groups of the calixarene and label the hydrophobic part in it.

Q4. a) Draw the diagrams for Soccer ball” cryptand molecule which acts as a cation host for + 4 NH ion as well as the diprotonated form acting as a host for H2O molecule. What makes the soccer ball crypates good hosts for anions?

b) Give any two suitable examples of two-dimensional hosts. Give examples of Zwiterionic hosts and amide based hosts. Which type of hosts can accommodate dicarboxylate anion guests?

Q5. a) What are the types of interactions that take place when hosts bind with guests? Why are neutral receptors accommodated by hosts?

b) Give the structure of the trimesic acid assembly. Which polyhalogen ions can this network accommodate? What sort of conformation of cyclotriveratrylene helps in forming inclusion compounds in solid state with benzene, toluene etc. Give suitable diagrams.

Q6. a) With the help of a suitable diagram explain the minimal self-replication model which is the key to life.

b) Discuss the mechanism of self-assembly in the Tobacco Mosaic Virus. What are the main non covalent ineractions that dominate biological self-assembly? Why self-assembly is essential in biology?

Q7. a) What are the advantageous of having synthetic models of biological systems? Differentiate between a structural mimic and a functional mimic.

b) Describe the three fundamental steps involved in natural and artificial photosynthesis. In what way supramolecular chemistry helps in designing artificial photosynthetic systems?

Q8. a) Differentiate between catalysis and cocatalysis in supramolecular chemistry. With the help of a suitable diagram give the schematic illustration of the cocatalysis process.

b) What are the essential characteristics of an effective carrier in supramolecular transport? What is electron-cation symport, and how is it achieved in supramolecular transport systems?

Q9. a) With the help of suitable diagrams give the differences between the structures of racks, ladders and grids.

b) What are metal-organic frameworks (MOFs)? What are other names of the organic ligands in them. Give examples of any two such frameworks.

Q10. a) With the help of suitable diagrams explain the synthesis of caternanes and rotaxanes via host guest chemistry.

b) What is supramolecular isomerism, and how does it relate to polymorphism? Explain the concept of rational design in supramolecular chemistry.

Frequently Asked Questions

Question 1. What is MCHE-013?

Answer: MCHE-013 is an IGNOU course titled Supramolecular Chemistry. It focuses on molecular recognition, non-covalent interactions, host–guest chemistry, self-assembly, and supramolecular systems.

Question 2. What is the assignment code for MCHE-013?

Answer: The assignment code for the 2026–27 Session is MCHE-013/TMA/2026-27.

Question 3. How many marks is the MCHE-013 assignment worth?

Answer: The MCHE-013 Tutor Marked Assignment carries a maximum of 10 marks.

Question 4. Which topics should students focus on for MCHE-013?

Answer: Students should focus on Supramolecular Chemistry, Non-Covalent Interactions, Molecular Recognition, Host–Guest Chemistry, Self-Assembly, Supramolecular Catalysis, Molecular Machines, and Applications of Supramolecular Systems.

Question 5. Why is MCHE-013 important?

Answer: MCHE-013 helps students understand how molecules interact and organize themselves through non-covalent forces to form complex supramolecular structures. It also introduces important applications in areas such as medicine, nanotechnology, catalysis, and materials science.

Need help preparing for MCHE – 013?

For updates, study guides, and academic assistance —  Visit myexamsolution.com WhatsApp 9310183377

• Tweet
• Share
• Share
• Share